Benzene, 1,3-diiodo- → HCID 178506545, compound

HRID 1838702Notes

Reaction equation

HRID 1838702 reaction equation
[C:1]([C-:3]1[CH:7]=[CH:6][CH:5]=[CH:4]1)#[CH:2].[CH-:8]1[CH:12]=[CH:11][CH:10]=[CH:9]1.[Fe+2:13].[I:14][C:15]1[CH:20]=[CH:19][CH:18]=[C:17](I)[CH:16]=1>>[C-:3]1([C:1]#[C:2][C:17]2[CH:18]=[CH:19][CH:20]=[C:15]([I:14])[CH:16]=2)[CH:7]=[CH:6][CH:5]=[CH:4]1.[CH-:8]1[CH:12]=[CH:11][CH:10]=[CH:9]1.[Fe+2:13]

Participants

3

Reactant 2

HCID 12270Benzene, 1,3-diiodo-HCID 15188896HCID 15188896, compound

Product 1

HCID 178506545HCID 178506545, compound

Procedure

Ethynylferrocene 500 was reacted with 1,3-diiodobenzene 502 to form 1-(ferrocenylethynyl)-3-iodobenzene 504. Sufficient ethynylferrocene 500 was present such that the second step of the reaction immediately proceeded. 1-(Ferrocenylethynyl)-3-iodobenzene 504 reacted with ethynylferrocene 514 to form 1,3-bis(ferrocenylethynyl) benzene 516. The reaction procedure is shown in FIG. 5.

Sources & evidence

ORD record
ord-3d2053327f064c7c880ea2ee71145e9d
Source dataset
uspto-grants-2004_01
Patent number
US06673953B2

Reaction notes

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