Sodium Azide → HCID 86158515, compound

HRID 1841872Notes

Reaction equation

HRID 1841872 reaction equation
[CH3:1][O:2][C:3](=[O:20])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18]Br.[N-:21]=[N+:22]=[N-:23].[Na+]>C(#N)C>[CH3:1][O:2][C:3](=[O:20])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][N:21]=[N+:22]=[N-:23]

Participants

4

Reactant 2

HCID 33557Sodium AzideHCID 2736822Methyl 16-bromohexadecanoate

Product 1

HCID 86158515HCID 86158515, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

16-bromohexadecanoic acid methyl ester is reacted with sodium azide in acetonitrile for four days at reflux temperature to give the corresponding azide (Zinic et al., Positionally Isomeric Organic Gelators: Structure-Gelation Study, Racemic versus Enantiomeric Gelators, and Solvation Effects, Chem. Eur. J. 2010; 16:3066-82).

Workup

  1. temperatureat reflux temperature

Sources & evidence

ORD record
ord-9e82479849424fd6ac2d50e6fd3911e4
Source dataset
uspto-grants-2015_02
Patent number
US08945897B2

Reaction notes

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