Hydrochloric Acid → 1-Methoxy-3-nonyl benzene

HRID 18450Notes

Reaction equation

HRID 18450 reaction equation
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][CH:6]=[C:5]([CH:9]=[CH:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17])[CH:4]=1.Cl>CCO.[Pd]>[CH3:1][O:2][C:3]1[CH:8]=[CH:7][CH:6]=[C:5]([CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17])[CH:4]=1

Participants

5

Reactant 2

HCID 313Hydrochloric AcidHCID 685864941-Methoxy-3-non-1-enyl benzene

Product 1

HCID 200388771-Methoxy-3-nonyl benzeneYield 100%

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

A solution of 1-methoxy-3-non-1-enyl benzene (7.4 g 32 mmol) in 99% EtOH (50 mL) was added 6 M HCl (aq.; 0.5 mL) and stirred with 10% Pd/C under H2-atmosphere (1 atm) to give 7.5 g (quantitative yield) of the desired product, after filtration through Celite and evaporation to dryness of the eluate.

Sources & evidence

ORD record
ord-501ca122717042c4b30a6e74dde14a62
Source dataset
uspto-grants-2010_06
Patent number
US07741352B2

Reaction notes

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