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HRID1852383

反应详情

EQUATION

反应方程式

HRID 1852383 的结构方程式

REACTANTS

反应物

2
结构：C[O-].[Na+]
HCID10942334

Methanol, sodium salt

CH3NaO

结构：CCOC(=O)CCCCCO[C@H]1O[C@H](COC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H]1OC(C)=O
HCID12151683

未命名化合物

PRODUCTS

生成物

1
结构：COC(=O)CCCCCO[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@@H]1O
HCID66848124

未命名化合物

收率 100%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CO
溶剂HCID887

Methanol

CH4O

PROCEDURE

实验过程

To compound 1 (3.7 g, 7.55 mmol) dissolved in 35 mL of anhydrous methanol, sodium methylate (1.6 g, 30.20 mmol) was added. After 30 min under stirring, cation exchange resin (Dowex® 50WX2, H+ form, 13 g) was added. After 1 h the resin was filtered and washed with methanol. The filtrate was concentrated under reduced pressure yielding 2 (2.1 g, 100%).

WORKUP

后处理

  1. additioncation exchange resin (Dowex® 50WX2, H+ form, 13 g) was added
  2. filtrationAfter 1 h the resin was filtered
  3. washwashed with methanol
  4. concentrationThe filtrate was concentrated under reduced pressure