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HRID1854322

反应详情

EQUATION

反应方程式

HRID 1854322 的结构方程式

REACTANTS

反应物

2
结构：CCOC(=O)C1(C)C[C@H](N(Cc2ccccc2)Cc2ccccc2)C[C@@H]1CC
HCID58010117

未命名化合物

结构：CCOC(=O)C1(C)C[C@@H](N(Cc2ccccc2)Cc2ccccc2)C[C@H]1CC
HCID58010228

未命名化合物

PRODUCTS

生成物

2
结构：CCOC(=O)C1(C)C[C@@H](N)C[C@H]1CC
HCID58009848

未命名化合物

结构：CCOC(=O)C1(C)C[C@H](N)C[C@@H]1CC
HCID58009886

未命名化合物

收率 100%

PROCEDURE

实验过程

A mixture of (2R,4S)-ethyl 4-(dibenzylamino)-2-ethyl-1-methylcyclopentanecarboxylate and (2S,4R)-ethyl 4-(dibenzylamino)-2-ethyl-1-methylcyclopentanecarboxylate (0.864 g, 2.28 mmol) was debenzylated using General Procedure FF to give (2R,4S)-ethyl 4-amino-2-ethyl-1-methylcyclopentanecarboxylate and (2S,4R)-ethyl 4-amino-2-ethyl-1-methylcyclopentanecarboxylate (0.45 g, 100%). LC/MS (Table 2, Method a) Rt=1.55 min; MS m/z: 200 (M+H)+.