Sodium ethoxide → HCID 86737133, compound

HRID 1855800Notes

Reaction equation

HRID 1855800 reaction equation
[CH3:1]/[C:2](/[CH:7]=[CH:8]/[CH:9]=[C:10](\[CH3:20])/[CH:11]=[CH:12]/[C:13]1[C:17]([CH3:18])=[CH:16][O:15][C:14]=1[CH3:19])=[CH:3]\[C:4](Cl)=[O:5].[O-:21]CC.[Na+:24]>CO>[CH3:1]/[C:2](/[CH:7]=[CH:8]/[CH:9]=[C:10](\[CH3:20])/[CH:11]=[CH:12]/[C:13]1[C:17]([CH3:18])=[CH:16][O:15][C:14]=1[CH3:19])=[CH:3]\[C:4]([O-:21])=[O:5].[Na+:24]

Participants

4

Reactant 2

HCID 2723922Sodium ethoxideHCID 88732654HCID 88732654, compound

Product 1

HCID 86737133HCID 86737133, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

(E,E,E,E)-3,7-dimethyl-9-(2,4-dimethyl-3-furyl)-2,4,6,8-nonatetraenoic acid chloride (1.5 g.) was dissolved in a solution of methanol and sodium ethoxide (0.3 g.) and the resulting mixture was then concentrated to dryness to give sodium (E,E,E,E)-3,7-dimethyl-9-(2,4-dimethyl-3-furyl)-2,4,6,8-nonatetraenoate m.p.~280° with decomposition as an amorphous solid.

Workup

  1. concentrationthe resulting mixture was then concentrated to dryness

Sources & evidence

ORD record
ord-3028a046c92c49fe9e8d7bfc67654864
Source dataset
uspto-grants-1980_08
Patent number
US04216312

Reaction notes

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