HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrochloric Acid → (2-{4-[(1-Hydroxyethylidene)amino]benzene-1-sulfonyl}hydrazinylidene)acetic acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | Glyoxylic acid, monohydrate | HCID 15620607 | — |
| Reactant | HCID 86737152 | HCID 86737152 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | (2-{4-[(1-Hydroxyethylidene)amino]benzene-1-sulfonyl}hydrazinylidene)acetic acid | HCID 321926 | — |
Reaction Steps
The subject compound is prepared using the general method of Example 1 except that 4.58 g (20 mmol) of glyoxylic acid p-acetamidobenzenesulfonylhydrazide was reacted with 2.4 g (26 mmol) of glyoxylic acid monohydrate in the presence of 1/2 cc conc. HCl and 200 cc acetonitrile. The desired product was obtained in a yield of 5.4 g, m.p. 136° (dec.).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04218465 |
| Source dataset | uspto-grants-1980_08 |
| ORD ID | ord-cbcbf5377c674adf8ad789d2649b79d3 |
| Source note | uspto-grants-1980_08 |