Hydrochloric Acid → HCID 18950271, compound

HRID 1856220Notes

Reaction equation

HRID 1856220 reaction equation
Cl[C:2]1[CH:10]=[CH:9][C:5]([C:6](O)=O)=[C:4]([Cl:11])[C:3]=1C.[CH:13]([O-:18])([O-])[O:14][CH2:15][CH3:16].[ClH:19]>C(O)C>[Cl:11][C:4]1[C:5]([CH3:6])=[C:9]([CH:10]=[CH:2][C:3]=1[Cl:19])[C:13]([O:14][CH2:15][CH3:16])=[O:18]

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 132359512,4-Dichloro-3-methylbenzoic acidHCID 53630039Ethylorthoformate

Product 1

HCID 18950271HCID 18950271, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

12.0 g. (0.058 mol.) of dichloro-3-methylbenzoic acid and 75 ml. of ethyl orthoformate in 100 ml. of ethanol was saturated with hydrogen chloride and refluxed to give ethyl 3,4-dichloro-2-methylbenzoate.

Workup

  1. temperaturerefluxed

Sources & evidence

ORD record
ord-6f3afbae7dbc4c8187f65b1d12814a89
Source dataset
uspto-grants-1980_08
Patent number
US04218464

Reaction notes

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