4-Nitrobenzoyl chloride → HCID 86737163, compound

HRID 1856503Notes

Reaction equation

HRID 1856503 reaction equation
[N+:1]([CH2:4][C:5]([CH3:9])=[CH:6][CH2:7][OH:8])([O-:3])=[O:2].[N+:10]([C:13]1[CH:21]=[CH:20][C:16]([C:17](Cl)=[O:18])=[CH:15][CH:14]=1)([O-:12])=[O:11]>C1C=CC=CC=1>[CH3:9][C:5]([CH2:4][N+:1]([O-:3])=[O:2])=[CH:6][CH2:7][OH:8].[N+:10]([C:13]1[CH:21]=[CH:20][C:16]([C:17]([O-:2])=[O:18])=[CH:15][CH:14]=1)([O-:12])=[O:11]

Participants

4

Reactant 2

HCID 85024-Nitrobenzoyl chlorideHCID 544391273-Methyl-4-nitrobut-2-en-1-ol

Product 1

HCID 86737163HCID 86737163, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

To 0.1 Mol of 4-nitro-3-methyl-2-butenol in benzene was added 0.1 Mol of p-Nitrobenzoylchloride and stirred overnight. The benzene was evaporated and the residue was stirred in sat. sodiumbicarbonate solution for 1 hour. The solid was filtered and recrystallized from hexane. An off white crystalline product, mp 63°-66° C., was obtained.

Workup

  1. customThe benzene was evaporated
  2. stirringthe residue was stirred in sat. sodiumbicarbonate solution for 1 hour
  3. filtrationThe solid was filtered
  4. customrecrystallized from hexane
  5. customAn off white crystalline product, mp 63°-66° C., was obtained

Sources & evidence

ORD record
ord-e942335fdd9b4ca3803a9297b9456fe4
Source dataset
uspto-grants-1980_08
Patent number
US04219660

Reaction notes

Loading…