Benzoyl chloride → HCID 86737168, compound

HRID 1856508Notes

Reaction equation

HRID 1856508 reaction equation
[N+:1]([CH2:4][C:5]([CH3:9])=[CH:6][CH2:7][OH:8])([O-:3])=[O:2].[C:10](Cl)(=[O:17])[C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1>C1C=CC=CC=1>[CH3:9][C:5]([CH2:4][N+:1]([O-:3])=[O:2])=[CH:6][CH2:7][OH:8].[C:10]([O-:17])(=[O:2])[C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1

Participants

4

Reactant 2

HCID 7412Benzoyl chlorideHCID 544391273-Methyl-4-nitrobut-2-en-1-ol

Product 1

HCID 86737168HCID 86737168, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

To 0.1 Mol of 4-nitro-3-methyl-2-butenol in benzene was added 0.09 Mol benzoylchloride and stirred overnight. The benzene was evaporated and the residue was stirred with sat. sodiumbicarbonate solution and extracted with ether. The oily product was purified by column chromatography, yielding the product as a slight yellow liquid.

Workup

  1. customThe benzene was evaporated
  2. stirringthe residue was stirred with sat. sodiumbicarbonate solution
  3. extractionextracted with ether
  4. customThe oily product was purified by column chromatography

Sources & evidence

ORD record
ord-f79df4868c1a45e8a4b8b7fd7579c944
Source dataset
uspto-grants-1980_08
Patent number
US04219660

Reaction notes

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