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HRID1858304

反应详情

EQUATION

反应方程式

HRID 1858304 的结构方程式

REACTANTS

反应物

1
结构：CC(C)(C)[Si](OCCc1ccc([N+](=O)[O-])cc1)(c1ccccc1)c1ccccc1
HCID22125112

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)(C)[Si](OCCc1ccc(N)cc1)(c1ccccc1)c1ccccc1
HCID22124994

未命名化合物

收率 94.9%

AUXILIARIES

试剂、催化剂与溶剂

2
结构：[Pd]
催化剂HCID23938

Palladium

Pd

结构：CO
溶剂HCID887

Methanol

CH4O

PROCEDURE

实验过程

A solution of 6.5 g (16 mmol) 4-[2-(tert-butyldiphenylsilyloxy)ethyl]nitrobenzene in methanol (30 ml) containing 750 mg of 10% palladium on carbon was hydrogenated at room temperature and atmospheric pressure for 2 hours. The catalyst was removed by filtration and the solvent evaporated to give 5.7 g of 4-[2-(tert-butyldiphenylsilyloxy)ethyl]phenylamine as a colorless liquid. [Mass spectrum (ESI) MH+ =376].

WORKUP

后处理

  1. customwas hydrogenated at room temperature
  2. customThe catalyst was removed by filtration
  3. customthe solvent evaporated