Trichlorosilane → HCID 22129125, compound

HRID 1858401Notes

Reaction equation

HRID 1858401 reaction equation
[C:1]([C:5]1[CH2:9][CH2:8][CH2:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2].[Cl:10][SiH:11]([Cl:13])[Cl:12]>>[C:1]([CH:5]1[CH2:9][CH2:8][CH2:7][CH:6]1[Si:11]([Cl:13])([Cl:12])[Cl:10])([CH3:4])([CH3:3])[CH3:2]

Participants

3

Reactant 2

HCID 24811TrichlorosilaneHCID 13414410HCID 13414410, compound

Product 1

HCID 22129125HCID 22129125, compoundYield 60%

Procedure

A one-liter autoclave equipped with a stirrer was charged in a nitrogen atmosphere with 50 grams (0.40 mol) of 1-tert-butylcyclopentene, 108 grams (0.80 mol) of trichlorosilane and 20 grams (82 mmol) of 1,1'-azobis(cyclohexane-1-carbonitrle) and the mixture was reacted at a temperature of 130° C. for 3 days. The resulting reaction mixture was purified by distillation thereby obtaining 62 grams (0.24 mol) of 2-tert-butylcyclopentyltrichlorosilane. The structure of the resulting product was identified by 1H-NMR.

Workup

  1. customA one-liter autoclave equipped with a stirrer
  2. customthe mixture was reacted at a temperature of 130° C. for 3 days
  3. customThe resulting reaction mixture
  4. distillationwas purified by distillation

Sources & evidence

ORD record
ord-0678b5569ad24150a9072d5790207887
Source dataset
uspto-grants-2000_11
Patent number
US06150549

Reaction notes

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