Bisphenol A diglycidyl ether → HCID 20393567, compound

HRID 1862919Notes

Reaction equation

HRID 1862919 reaction equation
[CH3:1][C:2]1([CH3:12])[CH2:7][CH:6]([NH:8][CH3:9])[CH2:5][C:4]([CH3:11])([CH3:10])[NH:3]1.[O:13]1[CH2:37][CH:14]1[CH2:15][O:16][C:17]1[CH:22]=[CH:21][C:20]([C:23]([C:26]2[CH:31]=[CH:30][C:29]([O:32][CH2:33][CH:34]3[O:36][CH2:35]3)=[CH:28][CH:27]=2)([CH3:25])[CH3:24])=[CH:19][CH:18]=1>CO>[OH:13][CH:14]([CH2:37][N:8]([CH3:9])[CH:6]1[CH2:7][C:2]([CH3:1])([CH3:12])[NH:3][C:4]([CH3:11])([CH3:10])[CH2:5]1)[CH2:15][O:16][C:17]1[CH:18]=[CH:19][C:20]([C:23]([C:26]2[CH:27]=[CH:28][C:29]([O:32][CH2:33][CH:34]([OH:36])[CH2:35][N:8]([CH:6]3[CH2:5][C:4]([CH3:11])([CH3:10])[NH:3][C:2]([CH3:12])([CH3:1])[CH2:7]3)[CH3:9])=[CH:30][CH:31]=2)([CH3:25])[CH3:24])=[CH:21][CH:22]=1

Participants

4

Reactant 2

HCID 2286Bisphenol A diglycidyl etherHCID 13657792N,2,2,6,6-Pentamethylpiperidin-4-amine

Product 1

HCID 20393567HCID 20393567, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

To 50 ml of methanol were added 3.4 g of 2,2,6,6-tetramethyl-4-methylaminopiperidine and 3.4 g of 2,2-bis[p-(2,3-epoxypropoxy)phenyl]propane; the mixture was then reacted in a manner similar to that described in Example 1, giving the desired compound in the form of a white powder. The compound had an Rf value of 0.50 on thin layer chromatography on silica gel developed with a 1:3:1 by volume mixture of methanol, ethyl acetate and triethylamine.

Workup

  1. customthe mixture was then reacted in a manner similar to

Sources & evidence

ORD record
ord-fb36422a78ba43ce89e8e2021c010db3
Source dataset
uspto-grants-1979_09
Patent number
US04166813

Reaction notes

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