p-Chlorothiophenol → HCID 20392578, compound

HRID 1863282Notes

Reaction equation

HRID 1863282 reaction equation
Br[CH:2]([C:7]1[CH:12]=[CH:11][C:10]([O:13][C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)=[CH:9][CH:8]=1)[C:3]([O:5][CH3:6])=[O:4].[Cl:20][C:21]1[CH:26]=[CH:25][C:24]([SH:27])=[CH:23][CH:22]=1>CO>[Cl:20][C:21]1[CH:26]=[CH:25][C:24]([S:27][CH:2]([C:7]2[CH:12]=[CH:11][C:10]([O:13][C:14]3[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=3)=[CH:9][CH:8]=2)[C:3]([O:5][CH3:6])=[O:4])=[CH:23][CH:22]=1

Participants

4

Reactant 2

HCID 7815p-ChlorothiophenolHCID 20392609HCID 20392609, compound

Product 1

HCID 20392578HCID 20392578, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

Methyl α-bromo-α-[p-(phenoxy)phenyl]acetate (6.42 g) is reacted with 3.61 g of 4-chlorothiophenol in methanol as in Example 16 to afford a yellow oil which solidifies on standing. Recrystallization from 50 ml of petroleum ether affords the product as white crystals, mp 66°-67.5° C.

Workup

  1. customto afford a yellow oil which
  2. customRecrystallization from 50 ml of petroleum ether

Sources & evidence

ORD record
ord-fb4d791c888c4b64aa67498e82df0ec7
Source dataset
uspto-grants-1979_09
Patent number
US04168385

Reaction notes

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