Potassium Hydroxide → HCID 20392599, compound

HRID 1863285Notes

Reaction equation

HRID 1863285 reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([S:8][CH:9]([C:14]2[CH:19]=[CH:18][C:17]([O:20][C:21]3[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=3)=[CH:16][CH:15]=2)[C:10]([O:12]C)=[O:11])=[CH:4][CH:3]=1.[OH-].[K+]>CO>[Cl:1][C:2]1[CH:3]=[CH:4][C:5]([S:8][CH:9]([C:14]2[CH:19]=[CH:18][C:17]([O:20][C:21]3[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=3)=[CH:16][CH:15]=2)[C:10]([OH:12])=[O:11])=[CH:6][CH:7]=1

Participants

4

Reactant 2

HCID 14797Potassium HydroxideHCID 20392578HCID 20392578, compound

Product 1

HCID 20392599HCID 20392599, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

A mixture of 3.55 g of methyl α-(p-chlorophenylthio)-α-[p-(phenoxy)phenyl]acetate, 20 ml of 20% KOH and 5 ml of methanol is refluxed overnight. The mixture is acidified and worked up to afford a light green solid which is crystallized from chloroform to yield the product as white crystals, mp 121°-125° C.

Workup

  1. temperatureis refluxed overnight
  2. customto afford a light green solid which
  3. customis crystallized from chloroform

Sources & evidence

ORD record
ord-83ddf36a99594f52a04681272702f7f2
Source dataset
uspto-grants-1979_09
Patent number
US04168385

Reaction notes

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