Ammonia → HCID 178494684, Verbindung

HRID 1863365Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1863365
Cl.[CH3:2][O:3][CH2:4][C:5](=[NH:9])OCC.[OH:10][CH2:11][C:12]([CH2:14]O)=O.[NH3:16]>>[CH3:2][O:3][CH2:4][C:5]1[NH:9][CH:14]=[C:12]([CH2:11][OH:10])[N:16]=1

Komponenten

4

Edukt 3

HCID 222AmmoniaHCID 670DihydroxyacetoneHCID 12816254Ethyl 2-methoxyethanecarboximidate hydrochloride

Produkt 1

HCID 178494684HCID 178494684, Verbindung

Versuchsvorschrift

A 307.2 gm. portion of ethyl 2-methoxyacetimidate hydrochloride [Rule, J. Chem. Soc. 113, 9 (1918)] and 180 gm. of 1,3-dihydroxyacetone in one liter of liquid ammonia are reacted as described in Example 3 giving the desired product as an oil. A crystalline picrate salt (m.p. 175°-178° C.) is obtained by heating the oily product and picric acid in water.

Quellen und Nachweise

ORD-Eintrag
ord-d4eb8d81ffe94f3588f8f363095c3347
Quelldatensatz
uspto-grants-1979_09
Patentnummer
US04168964

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