Ethyl xanthate → HCID 178423568, compound

HRID 1865518Notes

Reaction equation

HRID 1865518 reaction equation
Br[C:2]1[CH:7]=[CH:6][C:5]([CH3:8])=[CH:4][C:3]=1[NH2:9].C(O[C:13]([SH:15])=[S:14])C.[K]>CN(C=O)C>[SH:15][C:13]1[S:14][C:2]2[CH:7]=[CH:6][C:5]([CH3:8])=[CH:4][C:3]=2[N:9]=1

Participants

5

Reactant 3

HCID 8823Ethyl xanthateHCID 5462222PotassiumHCID 64220652-Bromo-5-methylaniline

Product 1

HCID 178423568HCID 178423568, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

The title compound was prepared using the method of example 239, starting with 2-bromo-5-methyl-phenylamine (244) (4.48 g, 24.0 mmol), O-ethylxanthic acid, potassium salt (Lancaster, 8.70 g, 54 mmol) in DMF (35 mL). The mercaptobenzothiazole 245 was obtained as an pale brown solid (2.31 g, 53%).

Workup

  1. customThe title compound was prepared

Sources & evidence

ORD record
ord-52bb7c3a62b6497daa6d0fb7df969495
Source dataset
uspto-grants-2009_12
Patent number
US07626033B2

Reaction notes

Loading…