Dimethylformamide → HCID 178424119, compound

HRID 1865551Notes

Reaction equation

HRID 1865551 reaction equation
Br[C:2]1[CH:7]=[C:6]([CH3:8])[CH:5]=[CH:4][C:3]=1N.C(O[C:13]([SH:15])=[S:14])C.[K].C[N:18](C=O)C>>[SH:15][C:13]1[S:14][C:2]2[CH:3]=[CH:4][CH:5]=[C:6]([CH3:8])[C:7]=2[N:18]=1

Participants

5

Reactant 4

HCID 6228DimethylformamideHCID 8823Ethyl xanthateHCID 114222-Bromo-4-methylanilineHCID 5462222Potassium

Product 1

HCID 178424119HCID 178424119, compound

Procedure

The title compound was prepared using the method of example 239, starting with 2-bromo-4-methyl-phenylamine (Acros) (27.9 g), O-ethylxanthic acid, potassium salt (Lancaster, 54 g) in DMF (250 mL). The mercaptobenzothiazole 340 was obtained as an pale brown solid (27 g). Recrystallization from CHCl3 gave pinkish white crystals (20 g).

Workup

  1. customThe title compound was prepared

Sources & evidence

ORD record
ord-37e4a70c7134406e805c8ba585161c51
Source dataset
uspto-grants-2009_12
Patent number
US07626033B2

Reaction notes

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