HCID 69056511, compound → HCID 69056714, compound

HRID 1867219Notes

Reaction equation

HRID 1867219 reaction equation
[CH3:1][C:2]1([CH3:15])[CH2:7][CH2:6][CH2:5][CH:4]([C:8]2([CH3:14])[CH:12]=[CH:11][CH:10]([CH3:13])[O:9]2)[CH2:3]1>[Pd]>[CH3:1][C:2]1([CH3:15])[CH2:7][CH2:6][CH2:5][CH:4]([C:8]2([CH3:14])[CH2:12][CH2:11][CH:10]([CH3:13])[O:9]2)[CH2:3]1

Participants

3

Reactant 1

HCID 69056511HCID 69056511, compound

Product 1

HCID 69056714HCID 69056714, compoundYield 68.3%

Reagents, catalysts & solvents 1

HCID 23938PalladiumCatalyst

Procedure

According to the procedure of example 2, by hydrogenation of 1.00 g (4.80 mmol) of 2-(3′,3′-dimethylcyclohexyl)-2,5-dimethyl-2,5-dihydrofuran in the presence of 100 mg (0.0940 mmol) of 10% palladium on activated charcoal. Kugelrohr distillation furnished at 65-70° C./0.1 mbar 690 mg (68%) of the title compound as a colorless odoriferous liquid.

Workup

  1. distillationKugelrohr distillation

Sources & evidence

ORD record
ord-9d3ab117ded04cf6ab4c0cbe04039083
Source dataset
uspto-grants-2009_12
Patent number
US07632790B2

Reaction notes

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