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HRID1868833

反应详情

EQUATION

反应方程式

HRID 1868833 的结构方程式

REACTANTS

反应物

1
结构：CC(C)(C)OC(=O)CNC(=O)C1=C(O)c2c(F)cccc2C(C)(C)C1=O
HCID67099689

未命名化合物

PRODUCTS

生成物

1
结构：CC1(C)C(=O)C(C(=O)NCC(=O)O)=C(O)c2c(F)cccc21
HCID57983524

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：O=C(O)C(F)(F)F
溶剂HCID6422

未命名化合物

PROCEDURE

实验过程

1,1-Dimethylethyl N-((5-fluoro-4-hydroxy-1,1-dimethyl-2-oxo-naphthalen-3-yl)carbonyl)glycinate (116 mg, 319 μmol) was stirred in TFA (5 mL) for 15 minutes. The solvent was then removed in vacuo, and the residue was partitioned between DCM and water. The DCM layer was removed, and the solvent was removed in vacuo to give the product as a light yellow solid. MS m/e=308 (M+H)+. Calculated for C15H14FNO5 307.09.

WORKUP

后处理

  1. customThe solvent was then removed in vacuo
  2. customthe residue was partitioned between DCM and water
  3. customThe DCM layer was removed
  4. customthe solvent was removed in vacuo