Carbon Tetrachloride → 1,3-Dichloro-5-(3,3-dichloro-allyloxy)-2-[3,3-dichloro-2-(4-trifluoromethyl-phenoxymethyl)-allyloxy]-benzene

HRID 1869147Notes

Reaction equation

HRID 1869147 reaction equation
C1(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.[C:20](Cl)(Cl)([Cl:22])[Cl:21].[Cl:25][C:26]1[CH:47]=[C:46]([O:48][CH2:49][CH:50]=[C:51]([Cl:53])[Cl:52])[CH:45]=[C:44]([Cl:54])[C:27]=1[O:28][CH2:29][C:30](=O)[CH2:31][O:32][C:33]1[CH:38]=[CH:37][C:36]([C:39]([F:42])([F:41])[F:40])=[CH:35][CH:34]=1>C(#N)C>[Cl:25][C:26]1[CH:47]=[C:46]([O:48][CH2:49][CH:50]=[C:51]([Cl:52])[Cl:53])[CH:45]=[C:44]([Cl:54])[C:27]=1[O:28][CH2:29][C:30]([CH2:31][O:32][C:33]1[CH:34]=[CH:35][C:36]([C:39]([F:42])([F:41])[F:40])=[CH:37][CH:38]=1)=[C:20]([Cl:22])[Cl:21]

Participants

5

Reactant 3

HCID 5943Carbon TetrachlorideHCID 11776TriphenylphosphineHCID 86613082HCID 86613082, compound

Product 1

HCID 866130861,3-Dichloro-5-(3,3-dichloro-allyloxy)-2-[3,3-dichloro-2-(4-trifluoromethyl-phenoxymethyl)-allyloxy]-benzene

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

312 mg of triphenylphosphine, 183 mg of carbon tetrachloride and 200 mg of 1-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-3-(4-trifluoromethyl-phenoxy)-propan-2-one are stirred in 3 ml of acetonitrile for 24 hours at 55° C. The reaction mixture is concentrated and the residue is purified over silica gel. The title compound is obtained.

Workup

  1. concentrationThe reaction mixture is concentrated
  2. customthe residue is purified over silica gel

Sources & evidence

ORD record
ord-7bae7ae803fa4315b91414a54d8fdc88
Source dataset
uspto-grants-2009_12
Patent number
US07638514B2

Reaction notes

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