Tripropylamine → HCID 18696299, compound

HRID 1870428Notes

Reaction equation

HRID 1870428 reaction equation
[Br:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15]Br.[CH2:17]([N:20]([CH2:24][CH2:25][CH3:26])[CH2:21][CH2:22][CH3:23])[CH2:18][CH3:19]>>[Br-:1].[Br-:1].[CH2:17]([N+:20]([CH2:24][CH2:25][CH3:26])([CH2:21][CH2:22][CH3:23])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][N+:20]([CH2:24][CH2:25][CH3:26])([CH2:21][CH2:22][CH3:23])[CH2:17][CH2:18][CH3:19])[CH2:18][CH3:19]

Participants

3

Reactant 2

HCID 7616TripropylamineHCID 169955Tetradecane, 1,14-dibromo-

Product 1

HCID 18696299HCID 18696299, compound

Procedure

3.56 g (10 mM) of -1,14-dibromotetradecane are added to 20 ml tripropylamine and held at 80/90° C. over night. The excess tertiary amine is evaporated under vacuum, and a minimal amount of ethanol is added to redissolve the derivative which is reprecipitated with ether. The derivative defined in the title is obtained by recrystallization in a isopropanol/iisopropylic ether mixture, M.P.=170° C.

Workup

  1. custom90° C.
  2. customThe excess tertiary amine is evaporated under vacuum
  3. additiona minimal amount of ethanol is added
  4. dissolutionto redissolve the derivative which
  5. customis reprecipitated with ether
  6. customis obtained by recrystallization in a isopropanol/iisopropylic ether mixture, M.P.=170° C.

Sources & evidence

ORD record
ord-85d46468523749d8b46995bead30fc9b
Source dataset
uspto-grants-2000_08
Patent number
US06096788

Reaction notes

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