Dodecylamine → dodecylsulfam

HRID 1871168Notes

Reaction equation

HRID 1871168 reaction equation
[CH2:1]([NH2:13])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].Cl[S:15]([OH:18])(=[O:17])=[O:16]>N1C=CC=CC=1>[CH2:1]([NH:13][S:15](=[O:17])(=[O:16])[OH:18])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]

Participants

4

Reactant 2

HCID 13583DodecylamineHCID 24638Chlorosulfonic acid

Product 1

HCID 204302dodecylsulfam

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Procedure

Dodecyl amine (0.1 mol) is added to a round bottom flask equipped with magnetic stirrer and dissolved in anhydrous pyridine. Next, chlorosulfonic acid (0.1 mol) is added dropwise with stirring to the chilled solution. The resulting product, dodecyl sulfamic acid, is then collected by filtration, washed with water and dried in an oven.

Workup

  1. customequipped with magnetic stirrer
  2. filtrationThe resulting product, dodecyl sulfamic acid, is then collected by filtration
  3. washwashed with water
  4. customdried in an oven

Sources & evidence

ORD record
ord-4a0656a235154da7be2d4933bc71ac83
Source dataset
uspto-grants-2000_08
Patent number
US06103131

Reaction notes

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