Phenylhydrazine → HCID 11003015, compound

HRID 1871390Notes

Reaction equation

[C:1]1([NH:7][NH2:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH3:9][O:10][C:11]1[CH:12]=[C:13]([C:19]2[C@H:28]3[C@H:23]([CH2:24][CH2:25][CH2:26][CH2:27]3)[C:22](=[O:29])N(C(C)(C)C)N=2)[CH:14]=[CH:15][C:16]=1[O:17][CH3:18]>>[CH3:9][O:10][C:11]1[CH:12]=[C:13]([C:19]2[C@H:28]3[C@H:23]([CH2:24][CH2:25][CH2:26][CH2:27]3)[C:22](=[O:29])[N:7]([C:1]3[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=3)[N:8]=2)[CH:14]=[CH:15][C:16]=1[O:17][CH3:18]

Participants

Reactant 2

HCID 7516Phenylhydrazine

HCID 70003128HCID 70003128, compound

Product 1

HCID 11003015HCID 11003015, compound

Procedure

Prepared from compound A (see starting compounds) and phenylhydrazine as described for compound 14. Crystallized from ethyl acetate/petroleum ether (60°-95° C.). M.p. 122°-124° C.

Workup

customCrystallized from ethyl acetate/petroleum ether (60°-95° C.)

Sources & evidence

ORD record: ord-59c631804fa84201a7cb0b019042be7e
Source dataset: uspto-grants-2000_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06103718

Reaction notes

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