HuagongsheHuagongshe Chemistry Print Report · For research reference only
3-Hydroxymethyl-1-(4-methoxy-benzenesulfonyl)-2,3,4,7-tetrahydro-1H-azepine-2-carboxylic acid tert butyl ester → 1-(4-Methoxy-benzenesulfonyl)-3-phenylsulfanylmethyl-2,3,4,7-tetrahydro-1H-azepine-2-carboxylic acid tert-butyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3-Hydroxymethyl-1-(4-methoxy-benzenesulfonyl)-2,3,4,7-tetrahydro-1H-azepine-2-carboxylic acid tert butyl ester | HCID 53896843 | — |
| Reactant | 1-(4-Methoxy-benzenesulfonyl)-3-phenylsulfanylmethyl-azepane-2-carboxylic acid tert-butyl ester | HCID 54310094 | — |
| Product | 1-(4-Methoxy-benzenesulfonyl)-3-phenylsulfanylmethyl-2,3,4,7-tetrahydro-1H-azepine-2-carboxylic acid tert-butyl ester | HCID 54009864 | — |
Reaction Steps
1-(4-Methoxy-benzenesulfonyl)-3-phenylsulfanylmethyl-2,3,4,7-tetrahydro-1H-azepine-2-carboxylic acid tert-butyl ester was synthesized from 3-Hydroxymethyl-1-(4-methoxy-benzenesulfonyl)-2,3,4,7-tetrahydro-1H-azepine-2-carboxylic acid tert butyl ester in the same manner as the procedures used for the preparation of 1-(4-Methoxy-benzenesulfonyl)-3-phenylsulfanylmethyl-azepane-2-carboxylic acid tert-butyl ester: MS (M+H)+ =490, (M+NH4)+ =507.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06107291 |
| Source dataset | uspto-grants-2000_08 |
| ORD ID | ord-7bb8bed0884a4c7fb6ccca1dac7fc824 |
| Source note | uspto-grants-2000_08 |