Chlorosulfonic acid → HCID 136333678, compound

HRID 1872320Notes

Reaction equation

HRID 1872320 reaction equation
[OH:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]2[C:9]3[NH:13][C:12]([C:14]([C:44]4[CH:49]=[CH:48][CH:47]=[CH:46][CH:45]=4)=[C:15]4[N:43]=[C:18]([C:19]([C:37]5[CH:42]=[CH:41][CH:40]=[CH:39][CH:38]=5)=[C:20]5[NH:36][C:23](=[C:24]([C:30]6[CH:35]=[CH:34][CH:33]=[CH:32][CH:31]=6)[C:25]6[CH:26]=[CH:27][C:28]=2[N:29]=6)[CH:22]=[CH:21]5)[CH:17]=[CH:16]4)=[CH:11][CH:10]=3)=[CH:4][CH:3]=1.[Zn:50].Cl[S:52]([OH:55])(=[O:54])=[O:53]>C(Cl)(Cl)Cl>[OH:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]2[C:9]3[NH:13][C:12]([C:14]([C:44]4[CH:49]=[CH:48][C:47]([S:52]([O-:55])(=[O:54])=[O:53])=[CH:46][CH:45]=4)=[C:15]4[N:43]=[C:18]([C:19]([C:37]5[CH:38]=[CH:39][C:40]([S:52]([O-:55])(=[O:54])=[O:53])=[CH:41][CH:42]=5)=[C:20]5[NH:36][C:23](=[C:24]([C:30]6[CH:35]=[CH:34][C:33]([S:52]([O-:55])(=[O:54])=[O:53])=[CH:32][CH:31]=6)[C:25]6[CH:26]=[CH:27][C:28]=2[N:29]=6)[CH:22]=[CH:21]5)[CH:17]=[CH:16]4)=[CH:11][CH:10]=3)=[CH:4][CH:3]=1.[Zn+2:50].[OH:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]2[C:9]3[NH:13][C:12]([C:14]([C:44]4[CH:49]=[CH:48][C:47]([S:52]([O-:55])(=[O:54])=[O:53])=[CH:46][CH:45]=4)=[C:15]4[N:43]=[C:18]([C:19]([C:37]5[CH:38]=[CH:39][C:40]([S:52]([O-:55])(=[O:54])=[O:53])=[CH:41][CH:42]=5)=[C:20]5[NH:36][C:23](=[C:24]([C:30]6[CH:35]=[CH:34][C:33]([S:52]([O-:55])(=[O:54])=[O:53])=[CH:32][CH:31]=6)[C:25]6[CH:26]=[CH:27][C:28]=2[N:29]=6)[CH:22]=[CH:21]5)[CH:17]=[CH:16]4)=[CH:11][CH:10]=3)=[CH:4][CH:3]=1.[Zn+2:50].[Zn+2:50]

Participants

4

Reactant 2

HCID 24638Chlorosulfonic acidHCID 136333680HCID 136333680, compound

Product 1

HCID 136333678HCID 136333678, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent2×

Procedure

To a mixture of 1 g of zinc 5-(4-hydroxyphenyl)-10,15,20-triphenylporphyrin and chloroform, there was added 60 μl of chlorosulfonic acid dissolved in 10 ml of chloroform at 0° C. After 12 h, the solution was poured on ice, and the organic phase was separated. Evaporation of the solvent yielded the product.

Workup

  1. additionthe solution was poured on ice
  2. customthe organic phase was separated
  3. customEvaporation of the solvent
  4. customyielded the product

Sources & evidence

ORD record
ord-b7aed0de72c345e39237fb33318f83ed
Source dataset
uspto-grants-2000_08
Patent number
US06107480

Reaction notes

Loading…