Methyl Methacrylate → HCID 136333678, compound

HRID 1872321Notes

Reaction equation

HRID 1872321 reaction equation
[OH:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]2[C:9]3[NH:13][C:12]([C:14]([C:52]4[CH:57]=[CH:56][C:55]([S:58]([O-:61])(=[O:60])=[O:59])=[CH:54][CH:53]=4)=[C:15]4[N:51]=[C:18]([C:19]([C:41]5[CH:46]=[CH:45][C:44]([S:47]([O-:50])(=[O:49])=[O:48])=[CH:43][CH:42]=5)=[C:20]5[NH:40][C:23](=[C:24]([C:30]6[CH:35]=[CH:34][C:33]([S:36]([O-:39])(=[O:38])=[O:37])=[CH:32][CH:31]=6)[C:25]6[CH:26]=[CH:27][C:28]=2[N:29]=6)[CH:22]=[CH:21]5)[CH:17]=[CH:16]4)=[CH:11][CH:10]=3)=[CH:4][CH:3]=1.CC(C(OC)=O)=C.C([O-])(=O)C.[Zn+2:73].C([O-])(=O)C>C(Cl)(Cl)Cl>[OH:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]2[C:9]3[NH:13][C:12]([C:14]([C:52]4[CH:57]=[CH:56][C:55]([S:58]([O-:61])(=[O:59])=[O:60])=[CH:54][CH:53]=4)=[C:15]4[N:51]=[C:18]([C:19]([C:41]5[CH:46]=[CH:45][C:44]([S:47]([O-:50])(=[O:49])=[O:48])=[CH:43][CH:42]=5)=[C:20]5[NH:40][C:23](=[C:24]([C:30]6[CH:35]=[CH:34][C:33]([S:36]([O-:39])(=[O:38])=[O:37])=[CH:32][CH:31]=6)[C:25]6[CH:26]=[CH:27][C:28]=2[N:29]=6)[CH:22]=[CH:21]5)[CH:17]=[CH:16]4)=[CH:11][CH:10]=3)=[CH:4][CH:3]=1.[Zn+2:73].[OH:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]2[C:9]3[NH:13][C:12]([C:14]([C:52]4[CH:57]=[CH:56][C:55]([S:58]([O-:61])(=[O:59])=[O:60])=[CH:54][CH:53]=4)=[C:15]4[N:51]=[C:18]([C:19]([C:41]5[CH:46]=[CH:45][C:44]([S:47]([O-:50])(=[O:49])=[O:48])=[CH:43][CH:42]=5)=[C:20]5[NH:40][C:23](=[C:24]([C:30]6[CH:35]=[CH:34][C:33]([S:36]([O-:39])(=[O:38])=[O:37])=[CH:32][CH:31]=6)[C:25]6[CH:26]=[CH:27][C:28]=2[N:29]=6)[CH:22]=[CH:21]5)[CH:17]=[CH:16]4)=[CH:11][CH:10]=3)=[CH:4][CH:3]=1.[Zn+2:73].[Zn+2:73]

Participants

5

Reactant 3

HCID 6658Methyl MethacrylateHCID 11192Zinc AcetateHCID 136333681HCID 136333681, compound

Product 1

HCID 136333678HCID 136333678, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

10 g of the 5-(4-hydroxyphenyl)-10,15,20-tris(4-sulfonatophenyl)porphyrin fixed to PMMA was dissolved in 200 ml of chloroform, and zinc acetate was added. After heating and evaporating the solvent, the desired polymer was isolated.

Workup

  1. temperatureAfter heating
  2. customevaporating the solvent

Sources & evidence

ORD record
ord-c9939fabe2374e6ca60e921cbd99a00f
Source dataset
uspto-grants-2000_08
Patent number
US06107480

Reaction notes

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