Cyclohexanone Oxime → HCID 524012, compound

HRID 1873099Notes

Reaction equation

HRID 1873099 reaction equation
[C:1]1(=[N:7][OH:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[C:9](OC(C)=C)(=[O:11])[CH3:10]>C1(C)C=CC=CC=1>[C:9]([O:8][N:7]=[C:1]1[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1)(=[O:11])[CH3:10]

Participants

4

Reactant 2

HCID 7517Cyclohexanone OximeHCID 7916Isopropenyl acetate

Product 1

HCID 524012HCID 524012, compoundYield 100%

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

A mixture of 2.3 g (20 mmole) of cyclohexanone oxime, 2.0 g (20 mmole) of isopropenyl acetate, 0.9 g (2 mmole) of di(η5 -pentamethylcyclopentadienyl)samarium [Cp*2Sm(THF)2 ], and 20 ml of toluene was stirred at room temperature for one hour, and the precipitated crystals were filtered. 3.1 g of acetyloxyiminocyclohexane (cyclohexanone oxime acetate) (yield: 100%) was obtained.

Workup

  1. filtrationthe precipitated crystals were filtered

Sources & evidence

ORD record
ord-e98dc018d15748db88bbbfc34cab5b4d
Source dataset
uspto-grants-2000_08
Patent number
US06111128

Reaction notes

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