An inositol → (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal

HRID 1879616Notes

Reaction equation

[CH:1]1([OH:12])[CH:6]([OH:7])[CH:5]([OH:8])[CH:4]([OH:9])[CH:3]([OH:10])[CH:2]1[OH:11].C(O)[C@H]1O[C@H](OC[C@H]2O[C@H](O[C@]3(CO)O[C@H](CO)[C@@H](O)[C@@H]3O)[C@H](O)[C@@H](O)[C@@H]2O)[C@H](O)[C@@H](O)[C@H]1O>>[O:7]=[CH:6][C@@H:5]([C@H:4]([C@@H:3]([C@@H:2]([CH2:1][OH:12])[OH:11])[OH:10])[OH:9])[OH:8]

Participants

Reactant 2

HCID 892An inositol

HCID 439242Raffinose

Product 1

HCID 107526(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal

Procedure

Comparing to the growth of the strain A34030 on a D-glucose-supplemented medium as a positive control, addition of L-arabinose, D-fructose, sucrose, D-xylose and D-mannitol gave a similar growth of the strain A34030, respectively. On the other hand, addition of myo-inositol gave lesser growth of the strain, and on rhamnose-supplemented medium, the growth was not observed. Addition of raffinose gave better growth of the strain A34030 than that of D-glucose.

Workup

customgave lesser growth of the strain

Sources & evidence

ORD record: ord-98876796182b4beb9b3ea04918e65333
Source dataset: uspto-grants-2012_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08318684B2

Reaction notes

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