Trichloroacetic Acid → HCID 57954477, compound

HRID 1879796Notes

Reaction equation

HRID 1879796 reaction equation
[O:1]1[CH2:6][CH2:5][C:4](=[N:7][OH:8])[CH2:3][CH2:2]1.C([O-])(=O)C.C([O-])(=O)C.C([O-])(=O)C.C([O-])(=O)C.[Pb+4].[Cl:26][C:27]([Cl:32])([Cl:31])[C:28]([OH:30])=[O:29]>>[Cl:26][C:27]([Cl:32])([Cl:31])[C:28]([O:30][C:4]1([N:7]=[O:8])[CH2:5][CH2:6][O:1][CH2:2][CH2:3]1)=[O:29]

Participants

4

Reactant 3

HCID 6421Trichloroacetic AcidHCID 12298558N-(oxan-4-ylidene)hydroxylamineHCID 178418268HCID 178418268, compound

Product 1

HCID 57954477HCID 57954477, compound

Procedure

4-Nitrosotetrahydro-2H-pyran-4-yl 2,2,2-trichloroacetate was prepared from tetrahydro-pyran-4-one oxime, lead tetraacetate and trichloroacetic acid using conditions of General Method 3. 1H NMR (360 MHz, chloroform-d) δ 3.99-4.19 (2H, m), 3.61-3.94 (2H, m), 2.30-2.61 (2H, m), 1.58-2.03 (2H, m).

Sources & evidence

ORD record
ord-7e0ba000aa1f4f098102057568282449
Source dataset
uspto-grants-2012_11
Patent number
US08318705B2

Reaction notes

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