Cyclohexanone Oxime → Diethyl 1-nitrosocyclohexyl phosphate

HRID 1879800Notes

Reaction equation

HRID 1879800 reaction equation
[C:1]1(=[N:7][OH:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.C([O-])(=O)C.C([O-])(=O)C.C([O-])(=O)C.C([O-])(=O)C.[Pb+4].[P:26]([O-:34])([O:31][CH2:32][CH3:33])([O:28][CH2:29][CH3:30])=[O:27]>>[P:26]([O:34][C:1]1([N:7]=[O:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1)([O:31][CH2:32][CH3:33])([O:28][CH2:29][CH3:30])=[O:27]

Participants

4

Reactant 3

HCID 7517Cyclohexanone OximeHCID 5166299Diethyl phosphoric acidHCID 178418268HCID 178418268, compound

Product 1

HCID 44479143Diethyl 1-nitrosocyclohexyl phosphate

Procedure

Diethyl 1-nitrosocyclohexyl phosphate was prepared from cyclohexanone oxime, lead tetraacetate and diethyl phosphate using conditions of General Method 3. 1H NMR (400 MHz, benzene-d6) δ 3.90-4.15 (3H, m), 1.24-1.78 (10H, m), 0.88-1.10 (7H, m)

Sources & evidence

ORD record
ord-0aee14d156aa43c79268ad6a701855e2
Source dataset
uspto-grants-2012_11
Patent number
US08318705B2

Reaction notes

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