HuagongsheHuagongshe Chemistry Print Report · For research reference only
Pivalic acid → 1,2,2,6,6-Pentamethyl-4-nitrosopiperidin-4-yl pivalate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Pivalic acid | HCID 6417 | — |
| Reactant | 1,2,2,6,6-Pentamethyl-piperidin-4-one oxime | HCID 241950 | — |
| Reactant | HCID 178418268 | HCID 178418268 | — |
| Product | 1,2,2,6,6-Pentamethyl-4-nitrosopiperidin-4-yl pivalate | HCID 57954471 | — |
Reaction Steps
1,2,2,6,6-Pentamethyl-4-nitrosopiperidin-4-yl pivalate was prepared from 1,2,2,6,6-pentamethyl-piperidin-4-one oxime, lead tetraacetate and trimethylacetic acid using conditions of General Method 3. 1H NMR (250 MHz, CHLOROFORM-d) δ 2.43-2.64 (5H, m), 2.09 (3H, s), 1.91 (2H, d, 14.2 Hz), 1.39 (6H, d, 5.9 Hz), 1.30 (9H, s), 1.25 (6H, d, 2.6 Hz).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08318705B2 |
| Source dataset | uspto-grants-2012_11 |
| ORD ID | ord-c47e4a33ebf44f39b0ce4364c49f4b18 |
| Source note | uspto-grants-2012_11 |