HRID188301

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID259

Bromide

Br-

HCID679

Dimethyl sulfoxide

C2H6OS

HCID962

Water

H2O

结构：CCCCC[P+](c1ccccc1)(c1ccccc1)c1ccccc1

HCID2724566

PENTYL-TRIPHENYL-PHOSPHANIUM

C23H26P+

HCID5360545

Sodium

HCID19855359

2-[3-(Benzyloxy)phenyl]-2-methylpropanal

C17H18O2

PRODUCTS

生成物

HCID54500852

1-(Benzyloxy)-3-(2-methyloct-3-en-2-yl)benzene

C22H28O

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-96e7f4e2ee3f4c648b258748b6999d38
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (6/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (6/10)

反应 SMILES

[Br-:2].[CH2:27]([c:28]1[cH:29][cH:30][cH:31][cH:32][cH:33]1)[O:34][c:35]1[cH:36][c:37]([C:41]([CH:42]=[O:43])([CH3:44])[CH3:45])[cH:38][cH:39][cH:40]1.[CH2:3]([CH2:4][CH2:5][CH2:6][CH3:7])[P+:8]([c:9]1[cH:10][cH:11][cH:12][cH:13][cH:14]1)([c:15]1[cH:16][cH:17][cH:18][cH:19][cH:20]1)[c:21]1[cH:22][cH:23][cH:24][cH:25][cH:26]1.[CH3:47][S:48](=[O:49])[CH3:50].[Na:1].[OH2:46]>>[CH:3]([CH2:4][CH2:5][CH2:6][CH3:7])=[CH:42][C:41]([c:37]1[cH:36][c:35]([O:34][CH2:27][c:28]2[cH:29][cH:30][cH:31][cH:32][cH:33]2)[cH:40][cH:39][cH:38]1)([CH3:44])[CH3:45]