Ammonium → HCID 178430028, compound

HRID 188376Notes

Reaction equation

HRID 188376 reaction equation
[Br:1][c:2]1[c:3](=[O:25])[n:4]([CH:19]2[O:20][CH2:21][CH2:22][CH2:23][CH2:24]2)[n:5][cH:6][c:7]1[NH:8][CH:9]1[CH:10]([CH3:18])[CH:11]2[C:12]([CH3:16])([CH3:17])[CH:13]([CH2:14]1)[CH2:15]2.[C:28]([P:29]([C:30]([CH3:31])([CH3:32])[CH3:33])[c:34]1[cH:35][cH:36][cH:37][cH:38][c:39]1-[c:40]1[c:41]([CH:42]([CH3:43])[CH3:44])[cH:45][c:46]([CH:47]([CH3:48])[CH3:49])[cH:50][c:51]1[CH:52]([CH3:53])[CH3:54])([CH3:55])([CH3:56])[CH3:57].[Cl-:58].[K+:27].[NH4+:59].[O:105]=[C:106]([CH:107]=[CH:108][c:109]1[cH:110][cH:111][cH:112][cH:113][cH:114]1)[CH:115]=[CH:116][c:117]1[cH:118][cH:119][cH:120][cH:121][cH:122]1.[O:61]1[CH2:62][CH2:63][O:64][CH2:65][CH2:66]1.[O:69]=[C:70]([CH:71]=[CH:72][c:73]1[cH:74][cH:75][cH:76][cH:77][cH:78]1)[CH:79]=[CH:80][c:81]1[cH:82][cH:83][cH:84][cH:85][cH:86]1.[O:87]=[C:88]([CH:89]=[CH:90][c:91]1[cH:92][cH:93][cH:94][cH:95][cH:96]1)[CH:97]=[CH:98][c:99]1[cH:100][cH:101][cH:102][cH:103][cH:104]1.[OH-:26].[OH2:60].[Pd:67].[Pd:68]>>[c:2]1([OH:26])[c:3](=[O:25])[n:4]([CH:19]2[O:20][CH2:21][CH2:22][CH2:23][CH2:24]2)[n:5][cH:6][c:7]1[NH:8][CH:9]1[CH:10]([CH3:18])[CH:11]2[C:12]([CH3:16])([CH3:17])[CH:13]([CH2:14]1)[CH2:15]2

Participants

11

Reactant 10

HCID 223AmmoniumHCID 312ChlorideHCID 813Potassium CationHCID 961HydroxideHCID 962WaterHCID 23938Palladium2×HCID 312751,4-DioxaneHCID 95417Dibenzylidene acetone3×HCID 11618717Di-tert-butyl(2',4',6'-tris(propan-2-yl)-(1,1'-biphenyl)-2-yl)phosphaneHCID 178430027HCID 178430027, compound

Product 1

HCID 178430028HCID 178430028, compound

Sources & evidence

ORD record
ord-d8d63f01719c4edfa8a7ab0065a1db0b
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Reaction notes

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