Ethyl Lactate → HCID 14692867, compound

HRID 1885107Notes

Reaction equation

HRID 1885107 reaction equation
[C:1]([O:6][CH2:7][CH3:8])(=[O:5])[CH:2]([CH3:4])[OH:3].[CH2:9](I)[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]>[Ag]=O>[CH2:9]([O:3][CH:2]([CH3:4])[C:1]([O:6][CH2:7][CH3:8])=[O:5])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]

Participants

4

Reactant 2

HCID 7344Ethyl LactateHCID 123801-Iodooctane

Product 1

HCID 14692867HCID 14692867, compoundYield 40.3%

Reagents, catalysts & solvents 1

HCID 92152Silver(II) oxideCatalyst

Procedure

98 g of ethyl lactate, 380 g of octyl iodide and 245 g of silver oxide were stirred at 60° C. for 16 hours. After removal of the insoluble matter by filtration, the mixture was distilled in vacuo to obtain 77 g of ethyl 2-octyloxypropionate as a fraction of 110°-130° C./3 mmHg.

Workup

  1. customAfter removal of the insoluble matter
  2. filtrationby filtration
  3. distillationthe mixture was distilled in vacuo

Sources & evidence

ORD record
ord-bb7287ac0fdc4af99df4de24aba8853d
Source dataset
uspto-grants-1992_09
Patent number
US05143643

Reaction notes

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