Hexanal → HCID 54555763, compound

HRID 1885411Notes

Reaction equation

[CH:1](=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6].Cl.[NH2:9][OH:10]>>[CH2:1]([N:9]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH3:6])[OH:10])[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6]

Participants

Reactant 2

HCID 6184Hexanal

HCID 443297Hydroxyamine hydrochloride

Product 1

HCID 54555763HCID 54555763, compoundYield 67.5%

Procedure

Following the general procedure of Example 2, hexanal (5.0 g, 50 mmol) is reacted with only one half equivalent of hydroxylamine hydrochloride (1.9 g, 28 mmol) to give 3.4 g of crude N,N-di-n-hexylhydroxylamine as a white solid which 90 1H NMR confirmed to be essentially only one compound. Purification of the crude product as described in Example 2 gives 2.0 g of the title compound as a white solid melting at 67° C.

Sources & evidence

ORD record: ord-9dc2069a37f04ac9a376518233a062e4
Source dataset: uspto-grants-1992_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05144075

Reaction notes

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