HRID1885680

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID24247

Perchloric acid

HClO4

HCID11346683

未命名化合物

HCID53986730

未命名化合物

PRODUCTS

生成物

结构：CCCCCCCCON1C(C)(C)CC(OCC(CO)OC2CC(C)(C)N(OCCCCCCCC)C(C)(C)C2)CC1(C)C

HCID23372126

未命名化合物

PROCEDURE

实验过程

The title compound is prepared by the reaction of 1-(1-octyloxy-2,2,6,6-tetramethylpiperidin-4-yloxy)-2,3-epoxypropane (prepared in Example 11) and 4-hydroxy-1-octyloxy-2,2,6,6-tetramethylpiperidine (prepared in Example 5) in the presence of a catalytic amount of perchloric acid.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-562fae1909c14e57ab400f9a92a0f28f
来源数据集: uspto-grants-1992_09
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05145893
来源说明: uspto-grants-1992_09

反应 SMILES

[CH2:1]([O:9][N:10]1[C:15]([CH3:17])([CH3:16])[CH2:14][CH:13]([O:18][CH2:19][CH:20]2[O:22][CH2:21]2)[CH2:12][C:11]1([CH3:24])[CH3:23])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[OH:25][CH:26]1[CH2:31][C:30]([CH3:33])([CH3:32])[N:29]([O:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH3:42])[C:28]([CH3:44])([CH3:43])[CH2:27]1.Cl(O)(=O)(=O)=O>>[CH2:35]([O:34][N:29]1[C:30]([CH3:32])([CH3:33])[CH2:31][CH:26]([O:25][CH:20]([CH2:19][O:18][CH:13]2[CH2:12][C:11]([CH3:24])([CH3:23])[N:10]([O:9][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8])[C:15]([CH3:16])([CH3:17])[CH2:14]2)[CH2:21][OH:22])[CH2:27][C:28]1([CH3:43])[CH3:44])[CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH3:42]