Ethanethiol → HCID 15129666, compound

HRID 1885917Notes

Reaction equation

HRID 1885917 reaction equation
C[O:2][C:3]1[CH:34]=[CH:33][C:6]2=[C:7]3[C:15](=[CH:16][CH:17]=[C:5]2[CH:4]=1)[C:14]1[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=1)[CH:8]3[C:18]1[CH:23]=[CH:22][C:21]([O:24][CH2:25][CH2:26][N:27]2[CH2:32][CH2:31][CH2:30][CH2:29][CH2:28]2)=[CH:20][CH:19]=1.[Cl-].[Al+3].[Cl-].[Cl-].C(S)C>ClCCCl>[OH:2][C:3]1[CH:34]=[CH:33][C:6]2=[C:7]3[C:15](=[CH:16][CH:17]=[C:5]2[CH:4]=1)[C:14]1[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=1)[CH:8]3[C:18]1[CH:23]=[CH:22][C:21]([O:24][CH2:25][CH2:26][N:27]2[CH2:32][CH2:31][CH2:30][CH2:29][CH2:28]2)=[CH:20][CH:19]=1

Participants

5

Reactant 3

HCID 6343EthanethiolHCID 6451240Aluminum(III) ChlorideHCID 9911574HCID 9911574, compound

Product 1

HCID 15129666HCID 15129666, compound

Reagents, catalysts & solvents 1

HCID 111,2-DichloroethaneSolvent

Conditions

Temperature
0 °C

Procedure

Two g of the compound of Example 12 was added to a suspension of 4.2 g of aluminum chloride and 2.8 g of ethanethiol in 50 ml of 1,2-dichloroethane at 0° C. The mixture was stirred for 2.5 hours at 0° C., and then worked up by the procedure used in Example 13. Thereby there was obtained 2.0 g of crystalline product. The product was recrystallized from acetone to obtain 1.71 g of the desired product, m.p. 216°-217° C.

Sources & evidence

ORD record
ord-21bc28ff4d4f40d7b4db00f0b5a3803a
Source dataset
uspto-grants-1992_09
Patent number
US05147880

Reaction notes

Loading…