Triphenylphosphine → HCID 21616553, compound

HRID 1886115Notes

Reaction equation

HRID 1886115 reaction equation
[F:1][C:2]([F:18])([F:17])[C:3]([C:5]1[CH:15]=[CH:14][C:8]([O:9][CH2:10][CH2:11][CH2:12][Br:13])=[CH:7][C:6]=1[OH:16])=[O:4].[C:19]1([P:25]([C:32]2[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=2)[C:26]2[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=2)[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1>>[Br-:13].[F:1][C:2]([F:18])([F:17])[C:3]([C:5]1[CH:15]=[CH:14][C:8]([O:9][CH2:10][CH2:11][CH2:12][P+:25]([C:26]2[CH:27]=[CH:28][CH:29]=[CH:30][CH:31]=2)([C:32]2[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=2)[C:19]2[CH:20]=[CH:21][CH:22]=[CH:23][CH:24]=2)=[CH:7][C:6]=1[OH:16])=[O:4]

Participants

3

Reactant 2

HCID 11776TriphenylphosphineHCID 19877024HCID 19877024, compound

Product 1

HCID 21616553HCID 21616553, compound

Procedure

The title compound is prepared analogously to Example 1c) from 3-(4-trifluoroacetyl-3-hydroxyphenoxy)-propyl bromide and triphenylphosphine; m.p. 125°-130° C.

Sources & evidence

ORD record
ord-e1d6f772ca6e42debc6e9e3f44570734
Source dataset
uspto-grants-1992_09
Patent number
US05149717

Reaction notes

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