Triphenylphosphine → HCID 21616521, compound

HRID 1886117Notes

Reaction equation

HRID 1886117 reaction equation
[C:1]([C:4]1[CH:9]=[CH:8][C:7]([S:10][CH2:11][CH2:12][CH2:13][Br:14])=[C:6]([CH2:15][CH2:16][CH3:17])[C:5]=1[OH:18])(=[O:3])[CH3:2].[C:19]1([P:25]([C:32]2[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=2)[C:26]2[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=2)[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1>>[Br-:14].[C:1]([C:4]1[CH:9]=[CH:8][C:7]([S:10][CH2:11][CH2:12][CH2:13][P+:25]([C:26]2[CH:27]=[CH:28][CH:29]=[CH:30][CH:31]=2)([C:32]2[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=2)[C:19]2[CH:20]=[CH:21][CH:22]=[CH:23][CH:24]=2)=[C:6]([CH2:15][CH2:16][CH3:17])[C:5]=1[OH:18])(=[O:3])[CH3:2]

Participants

3

Reactant 2

HCID 11776TriphenylphosphineHCID 157123831-{4-[(3-Bromopropyl)sulfanyl]-2-hydroxy-3-propylphenyl}ethan-1-one

Product 1

HCID 21616521HCID 21616521, compound

Procedure

The title compound is prepared analogously to Example 1 from 3-(4-acetyl-3-hydroxy-2-propylphenylthio)-propyl bromide and triphenylphosphine.

Sources & evidence

ORD record
ord-24527960d1f64628acb2319c7b2f6aa2
Source dataset
uspto-grants-1992_09
Patent number
US05149717

Reaction notes

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