Triphenylphosphine → HCID 21616548, compound

HRID 1886118Notes

Reaction equation

[C:1]([C:4]1[CH:9]=[CH:8][C:7]([S:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][Br:16])=[C:6]([CH2:17][CH2:18][CH3:19])[C:5]=1[OH:20])(=[O:3])[CH3:2].[C:21]1([P:27]([C:34]2[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=2)[C:28]2[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=2)[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1>>[Br-:16].[C:1]([C:4]1[CH:9]=[CH:8][C:7]([S:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][P+:27]([C:28]2[CH:29]=[CH:30][CH:31]=[CH:32][CH:33]=2)([C:34]2[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=2)[C:21]2[CH:22]=[CH:23][CH:24]=[CH:25][CH:26]=2)=[C:6]([CH2:17][CH2:18][CH3:19])[C:5]=1[OH:20])(=[O:3])[CH3:2]

Participants

Reactant 2

HCID 11776Triphenylphosphine

HCID 15712402HCID 15712402, compound

Product 1

HCID 21616548HCID 21616548, compound

Procedure

The title compound is prepared analogously to Example 1 from 5-(4-acetyl-3-hydroxy-2-propylphenylthio)-pentyl bromide and triphenylphosphine.

Sources & evidence

ORD record: ord-ba266c7ffe484396807558b2f42bdf0a
Source dataset: uspto-grants-1992_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05149717

Reaction notes

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