反应详情

3.6 g (30 mmol) of diethylaminopropyllithium dissolved in 100 ml of pentane are added to a solution of 4 g (30 mmol) of dimethylgallium chloride in 50 ml of pentane at -78°. The solution is allowed to come to room temperature and is stirred for a further 24 hours. The working up is carried out analogously to Example 1. Instead of the distillation, a sublimination is carried out. Diethylaminopropyl(dimethyl)gallium with an M.p. of 43°-45° is obtained.

1. customto come to room temperature
2. distillationInstead of the distillation