Dibenzosuberone → HCID 53961708, compound

HRID 1886549Notes

Reaction equation

HRID 1886549 reaction equation
[CH2:1]1[C:16]2[C:11](=[CH:12][CH:13]=[CH:14][CH:15]=2)[C:9](=O)[C:8]2[C:3](=[CH:4][CH:5]=[CH:6][CH:7]=2)[CH2:2]1.[CH2:17]([O:19]C=C[Li])[CH3:18]>C1COCC1>[CH:4]1[C:3]2[C:2]3[CH2:1][CH2:16][CH:15]=[CH:14][C:13]=3[CH:12]=[CH:11][C:9](=[CH:18][CH:17]=[O:19])[C:8]=2[CH:7]=[CH:6][CH:5]=1

Participants

4

Reactant 2

HCID 14589DibenzosuberoneHCID 178506908HCID 178506908, compound

Product 1

HCID 53961708HCID 53961708, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

Dibenzosuberone (5.3 g, 0.026 mol) was reacted with 1-ethoxy-2-lithio ethylene in anhydrous THF in the manner of Preparation 1 to yield present title product as a yellow oily solid, 2.86 g (48%).

Sources & evidence

ORD record
ord-93405fa244504e28b89dd01491e3bcad
Source dataset
uspto-grants-1992_09
Patent number
US05151545

Reaction notes

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