HRID1893158

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID176

Acetic Acid

C2H4O2

HCID1118

Sulfuric acid

H2O4S

HCID7918

Acetic anhydride

C4H6O3

结构：C=CC1(CO[Si](c2ccccc2)(c2ccccc2)C(C)(C)C)OC2OC(C)(C)OC2C1OCc1ccccc1

HCID67360139

未命名化合物

PRODUCTS

生成物

结构：C=CC1(C(O[SiH2]C(C)(C)C)(c2ccccc2)c2ccccc2)OC(OC(C)=O)C(OC(C)=O)C1OCc1ccccc1

HCID131730809

未命名化合物

收率 85%

PROCEDURE

实验过程

A flask was charged with (6-Benzyloxy-2,2-dimethyl-5-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-ylmethoxy)-tert-butyl-diphenyl-silane, Acetic acid, acetic acid anhydride, and H2SO4. The reaction was stirred, extracted, and the solvent was evaporated to provide the titled compound in 85% yield.

WORKUP

后处理

extractionextracted
customthe solvent was evaporated

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-6202bd376f074e4db2347946b0153ca5
来源数据集: uspto-grants-2013_08
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08513214B2
来源说明: uspto-grants-2013_08

反应 SMILES

[CH2:1]([O:8][CH:9]1[CH:16]2[CH:12]([O:13][C:14]([CH3:18])(C)[O:15]2)[O:11][C:10]1([CH2:21][O:22][Si:23]([C:36]([CH3:39])([CH3:38])[CH3:37])(C1C=CC=CC=1)C1C=CC=CC=1)[CH:19]=[CH2:20])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C([O:43][C:44](=[O:46])[CH3:45])(=O)C.OS(O)(=O)=O.[C:52](O)(=O)[CH3:53]>>[C:44]([O:43][CH:16]1[CH:9]([O:8][CH2:1][C:2]2[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=2)[C:10]([C:21]([C:53]2[CH:52]=[CH:19][CH:10]=[CH:9][CH:16]=2)([C:2]2[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=2)[O:22][SiH2:23][C:36]([CH3:37])([CH3:39])[CH3:38])([CH:19]=[CH2:20])[O:11][CH:12]1[O:13][C:14](=[O:15])[CH3:18])(=[O:46])[CH3:45]