4-Chlorophenol → 4-Chlorophenyl Sulfamate

HRID 1893620Notes

Reaction equation

[CH:1]1([O:4][S:5](=[O:8])(=[O:7])[NH2:6])[CH2:3][CH2:2]1.[Cl:9][C:10]1[CH:15]=[CH:14][C:13](O)=[CH:12][CH:11]=1>>[Cl:9][C:10]1[CH:15]=[CH:14][C:13]([NH:6][S:5](=[O:8])(=[O:7])[O-:4])=[CH:12][CH:11]=1.[Cl:9][C:10]1[CH:11]=[CH:12][C:1]([O:4][S:5](=[O:8])(=[O:7])[NH2:6])=[CH:3][CH:2]=1

Participants

Reactant 2

HCID 46844-Chlorophenol

HCID 57785190Cyclopropyl sulfamate

Product 2

HCID 101044834-Chlorophenyl Sulfamate

HCID 866327894-Chlorophenylsulfamate

Procedure

4-Chlorophenylsulfamate was synthesized according to the method presented in the synthesis of Sulfamic acid cyclopropyl ester in Example 1 with the exception of utilizing 4-chlorophenol to obtain sulfamic acid 4-chloro-phenyl ester.

Sources & evidence

ORD record: ord-ffe892e1a9b04b4f955b49f9d867c37b
Source dataset: uspto-grants-2013_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08513186B2

Reaction notes

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