5-Hexene-2-one → HCID 86663147, compound

HRID 1894279Notes

Reaction equation

HRID 1894279 reaction equation
[NH:1]([C:3]1[CH:8]=[CH:7][NH:6][C:5](=[O:9])[CH:4]=1)[NH2:2].[CH3:10][C:11](=O)[CH2:12][CH2:13][CH:14]=[CH2:15]>>[CH3:15][C:14](=[N:2][NH:1][C:3]1[CH:8]=[CH:7][NH:6][C:5](=[O:9])[CH:4]=1)[CH2:13][CH2:12][CH:11]=[CH2:10]

Participants

3

Reactant 2

HCID 79895-Hexene-2-oneHCID 136108294-Hydrazinylpyridin-2(1H)-one

Product 1

HCID 86663147HCID 86663147, compoundYield 71.3%

Procedure

In accordance with the same procedures as in Step 2 of Preparation 1, except for using 4-hydrazino-1H-pyridin-2-one (5.39 g, 43.1 mmol) prepared in Step 1 of Preparation 1 and 5-hexen-2-one (7.41 ml, 64.6 mmol), the titled compound was obtained as a white solid. (Yield: 71.3%)

Workup

  1. customIn accordance with the same procedures as in Step 2 of Preparation 1

Sources & evidence

ORD record
ord-b7dfcde17a2445578b92531429943991
Source dataset
uspto-grants-2013_08
Patent number
US08513277B2

Reaction notes

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