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HRID1895834

反应详情

EQUATION

反应方程式

HRID 1895834 的结构方程式

REACTANTS

反应物

3
反应SMILES：CCO
HCID702

Ethanol

C2H6O

反应SMILES：CC(C)(C)P(Cc1cccc(CP(C(C)(C)C)C(C)(C)C)c1)C(C)(C)C
HCID4188717

[1,3-Phenylenebis(methylene)]bis(di-tert-butylphosphane)

C24H44P2

反应SMILES：O.[Cl][Ru]([Cl])[Cl]
HCID6093376

未命名化合物

PRODUCTS

产物

1
反应SMILES：CC(C)(C)P(CC1=CC=CC(CP(C(C)(C)C)C(C)(C)C)(C(=O)[Ru]Cl)C1)C(C)(C)C
HCID178454873

未命名化合物

PROCEDURE

实验过程

Refluxing 1,3-bis((ditertiarybutylphosphino)methyl)benzene with ruthenium(III)chloride hydrate in ethanol produced the known complex 1,3-bis((ditertiarybutylphosphino)methyl)benzene(carbonyl)chlororuthenium(II). The carbonyl ligand is formed by decarbonylation of the ethanol solvent.