HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethanol → HCID 178454873, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethanol | HCID 702 | — |
| Reactant | [1,3-Phenylenebis(methylene)]bis(di-tert-butylphosphane) | HCID 4188717 | — |
| Reactant | Ruthenium trichloride hydrate | HCID 6093376 | — |
| Product | HCID 178454873 | HCID 178454873 | — |
Reaction Steps
Refluxing 1,3-bis((ditertiarybutylphosphino)methyl)benzene with ruthenium(III)chloride hydrate in ethanol produced the known complex 1,3-bis((ditertiarybutylphosphino)methyl)benzene(carbonyl)chlororuthenium(II). The carbonyl ligand is formed by decarbonylation of the ethanol solvent.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08518368B2 |
| Source dataset | uspto-grants-2013_08 |
| ORD ID | ord-a8c503c6d3cf4e83b3ec0f3f7da5af14 |
| Source note | uspto-grants-2013_08 |