Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Diphenyl Ether | HCID 7583 | — |
| Reactant | Tributylamine | HCID 7622 | — |
| Reactant | HCID 14994647 | HCID 14994647 | — |
| Solvent | Hexane | HCID 8058 | — |
| Product | HCID 14994648 | HCID 14994648 | — |
Reaction Steps
A suspension of (2E)-3-(1-benzothien-2-yl)acryloyl azide in diphenyl ether (9.2 equiv) and Bu3N (1.1 equiv) was heated to reflux for 1 h. A solution resulted. The mixture was cooled to 40-50° C. Hexane was added; the mixture was stirred for 30 min, filtered, and washed with hexanes to give the title compound as a yellow solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US08518964B2 |
|---|
| Source dataset | uspto-grants-2013_08 |
|---|
| ORD ID | ord-cccb7ab49ebc4e1ab9c81d03b5a493ba |
|---|
| Source note | uspto-grants-2013_08 |
|---|
