HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Butanol → Octanal
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Butanol | HCID 263 | — |
| Reactant | 1-Octanol | HCID 957 | — |
| Solvent | (+-)-2-Butanol | HCID 6568 | — |
| Product | Octanal | HCID 454 | — |
Reaction Steps
Simple aliphatic alcohols such as 1-butanol and 2-butanol underwent little or no oxidation, even when heated at 100° C. (Entries 18 and 19). This observed selectivity for activated alcohols was confirmed by oxidation of a mixture of 4-methoxybenzylic alcohol (5 mmol) and 1-octanol (5 mmol), which resulted in complete oxidation of the benzylic alcohol with no formation of 1-octanal.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08519132B2 |
| Source dataset | uspto-grants-2013_08 |
| ORD ID | ord-ce022f5931f04663b74a453fed253229 |
| Source note | uspto-grants-2013_08 |